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Kinetic Studies of the Reactions of Si:C and Si:Si Bonds

✍ Scribed by Tracy L. Morkin; Thomas R. Owens; William J. Leigh


Publisher
John Wiley and Sons
Year
2003
Weight
54 KB
Volume
34
Category
Article
ISSN
0931-7597

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Pentacoordination of Silicon by Four Cov
✍ Reinhold Tacke; Matthias Mallak; Reiner Willeke πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 82 KB

The zwitterionic compounds 1 and 2 are the first pentacoordinate silicates with covalent SiS C skeletons. They were characterized by crystal-structure analyses and NMR spectroscopic studies. Although pentacoordination of silicon is usually favored by ligand atoms of high electronegativity, the struc