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ChemInform Abstract: Kinetics and Mechanisms of the Reactions of Si=C and Ge=C Double Bonds

✍ Scribed by William J. Leigh


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
30
Category
Article
ISSN
0931-7597

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Addition reactions of the diarylgermylene R 2 Ge: 5, C 6 H) and the heteroleptic stannylene RRЈSn: (RЈ ‫ב‬ Si(SiMe 3 ) 3 ) to the cryptodiborylcarbene (Me 3 Si) 2 C(tBuB) 2 C: furnish the germaethene (Me 3 Si) 2 C(tBuB) 2 C‫ב‬GeR 2 (8) and the stannaethene (Me 3 Si) 2 C(tBuB) 2 C‫ב‬SnRRЈ (12), respe