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Intrinsic Bond Strengths of Multiple C−C, Si−Si, and C−Si Bonds

✍ Scribed by Jörg Grunenberg


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
71 KB
Volume
40
Category
Article
ISSN
0044-8249

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The zwitterionic compounds 1 and 2 are the first pentacoordinate silicates with covalent SiS C skeletons. They were characterized by crystal-structure analyses and NMR spectroscopic studies. Although pentacoordination of silicon is usually favored by ligand atoms of high electronegativity, the struc