Kinetic studies of the reaction of CN with H2O from 518 to 1027 K
β Scribed by A. Jacobs; M. Wahl; R. Weller; J. Wolfrum
- Book ID
- 107733245
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 382 KB
- Volume
- 144
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
We have extended the highly precise laser photolysis/cw laser-induced fluorescence technique to the study of CN-radical reaction kinetics. We investigated the reaction of CN with O2 over the temperature range 295-7 IO K. The measured reaction-rate coeflicients are well represented over this temperat
The reaction between CzH5 and 0 2 a t 295 K has been studied with a flow reactor sampled by a mass spectrometer. With helium as the carrier gas the rate coefficient was found to increase from (1.2 f 0.3) X cm3/s as [He] was increased from 2 X 10I6 to 3.4 X 1017 The importance of to (3.6 f 0.9) has
## Abstract The reaction of H radical with C~2~H~5~CN has been studied using various quantum chemistry methods. The geometries were optimized at the B3LYP/6β311+G(d,p) and B3LYP/6β311++G(2d,2p) levels. The singleβpoint energies were calculated using G3 and BMCβCCSD methods based on B3LYP/6β311++G(2