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Kinetic studies of the formation and dissociation reactions of copper(II) bisdien complexes.

✍ Scribed by M.R. McDonald; B. Dietrich; M.W. Hosseini; J.M. Lehn; R.W. Taylor

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
64 KB
Volume
43
Category
Article
ISSN
0162-0134

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## Abstract The stopped‐flow technique was used to measure the rates of formation and dissociation of tetrahedral [ML~2~] complexes (M^2+^=Ni^2+^ or Co^2+^) of four bidentate S~2~‐donor ‘dithioimidodiphosphato’ ligands L^−^ (HL=[R^1^R^2^P(S)]NH[P(S)R^3^R^4^], R^1^ to R^4^=alkyl) at 25.0° in MeOH/