Model Complexes for Ureases: A Dinickel(
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Birgit Hommerich; Hendrik Schwöppe; Dirk Volkmer; Bernt Krebs
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Article
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1999
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John Wiley and Sons
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German
⚖ 163 KB
👁 2 views
The dinuclear nickel(II) complex of the asymmetric ligand 1-[N,N-bis(2-pyridylmethyl)amino]-3-[2-(3,5dimethyl-1H-pyrazol-1-yl)ethoxy]-2-hydroxypropane (HL1) was prepared as a model for the active site of urease. The novel complex [Ni 2 (L1)(MeCOO)(ClO 4 )(EtOH) 2 ](ClO 4 ) 0.5 Et 2 O (1) crystallize