Kinetic studies of O3 reactions with 3-bromopropene and 3-iodopropene in the temperature range 288–328 K
✍ Scribed by Yanbo Gai; Maofa Ge; Weigang Wang
- Book ID
- 113478827
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 240 KB
- Volume
- 43
- Category
- Article
- ISSN
- 1352-2310
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📜 SIMILAR VOLUMES
Kate constants for the reaction O(3P) + SO2 + M have been determined over the temperature range of 299"-440"K, using a flash photolysis-NO2 chemiluminescence technique. For M=Ar, the Arrhenius expression k2Ar = 3.1 X 10-32e-'2005\*3")'RT cm6/molec2 ~ sec was obtained. A t room temperature kqAr = (1.
The reactions of CH3 radicals with O(3P) and 0 2 have been studied at 295 K in a gas flow reactor sampled by a mass spectrometer. For the reaction between CH3 and 0, conditions were such that [O] >> [CH3] and the methyl radicals decayed under pseudo-first-order conditions giving a rate coefficient o
## Abstract A laser flash photolysis–resonance fluorescence technique has been employed to investigate the kinetics of the reaction of ground state oxygen atoms, O(^3^__P__~J~), with (CH~3~)~2~SO (dimethylsulfoxide) as a function of temperature (266–383 K) and pressure (20–100 Torr N~2~). The rate
## Abstract Rate constants for the reactions of OH and NO~3~ radicals with CH~2~CHF (__k__~1~ and __k__~4~), CH~2~CF~2~ (__k__~2~ and __k__~5~), and CHFCF~2~ (__k__~3~ and __k__~6~) were determined by means of a relative rate method. The rate constants for OH radical reactions at 253–328 K were