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Kinetic studies of chloro-p-nitrophenylcarbene with acetone and diethyl fumarate

✍ Scribed by Michael T.H Liu; N Soundararajan; Surinder M Anand; Toshikazu Ibata

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
225 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

The reaction of chloro-p-nitrophenylcarbene with acetone to form carbonyl ylide is not reversible.

The formation of carbonyl ylide through the carbene-cerbonyl reaction and the trapping of the carbonyl ylide as 1,3-dipolar cycloadduct by various substrates were reported. 1

However, the kinetics of such systems has not been researched to date, even though the

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