Kinetics and mechanism of oxidation of acetone, ethyl methyl ketone and diethyl ketone with chloramine-T in hydrochloric acid medium
โ Scribed by H. M. K. Naidu; D. S. Mahadevappa
- Publisher
- Springer Vienna
- Year
- 1978
- Tongue
- English
- Weight
- 335 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0026-9247
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๐ SIMILAR VOLUMES
The kinetics of oxidation of five amines viz., ethylenediamine (EDA), diethylenetriamine (DETA), triethylenetetramine (TETA), aminoethylpiperazine (AEP) and isophoronediamine (IPDA) by sodium N-chloro-p-toluenesulfonamide or chloramine-T (CAT) in the presence of HCl and Ru(III) chloride was studied
The kinetics and mechanism of Os(VIl1) utalysed oxidation of some suhstituted transcinnnmic acids by chlonmine-T in presence of alkaline medium has been investigated. The order with respect to [CAT] is zero and is lOsO ] one. The reaction is fractional order in [substrate]. The rate dependace on [OH