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Kinetics and mechanism of oxidation of aryl β-styryl ketones by osmium tetroxide in sulphuric acid-acetic acid medium. A structure-reactivity correlation study

✍ Scribed by Puppala Veera Somaiah; Kedika Bal Reddy; Bangalore Sethuram; Tangeda Navaneeth Rao

Publisher: Springer
Year: 1993
Tongue: English
Weight: 269 KB
Volume: 18
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf00136051

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Kinetics and mechanism of oxidation ofα,β-unsaturated alcohols by manganese(III) acetate in aqueous sulphuric acid medium

✍ S. Pulla Rao; M. Anand Rao 📂 Article 📅 1993 🏛 Springer 🌐 English ⚖ 329 KB

The kinetics of oxidation of c~,/?-unsaturated alcohols (UA's), such as prop-2-ene-l-ol, but-2-ene-l-ol and 3phenyl-prop-2-ene-l-ol, by manganese(III) acetate in aqueous H2SO 4 at constant ionic strength and different acidities has been studied. The reaction was found to proceed through an outer sph