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Kinetic Resolution of Heteroaryl β-Hydroxy Sulfides Catalyzed by Humicola lanuginosa Lipase.

✍ Scribed by Swapandeep Singh Chimni; Satwinder Singh; Subodh Kumar; Savita Mahajan

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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ChemInform Abstract: Humicola lanuginosa
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✍ Satwinder Singh; Subodh Kumar; Swapandeep Singh Chimni 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB

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Chemoenzymatic dynamic kinetic resolution of b-hydroxy nitriles 1 has been carried out using Candida antarctica lipase B and a ruthenium catalyst. The use of a hydrogen source to depress ketone formation in the dynamic kinetic resolution yields the corresponding acetates 2 in good yield and high ena