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ChemInform Abstract: Kinetic Resolution of Hydroxy Vinylsilanes by Lipase-Catalyzed Enantioselective Acetylation.

โœ Scribed by W. ADAM; C. MOCK-KNOBLAUCH; C. R. SAHA-MOELLER

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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The lipase-catalyzed acetylation of a broad spectrum of configurations of the 2-hydroxy acids 1 were assigned by comparison of the gas-chromatographic data with that of racemic 2-hydroxy acids 1 to their 2-acetoxy acids 2 was shown to proceed with high enantioselectivity. Thus, the literature-known