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Kinetic regularities of catalytic ethylene polymerization on single- and multi-site cobalt and vanadium bis(imino)pyridine complexes

✍ Scribed by A. A. Barabanov, N. V. Semikolenova, M. A. Mats’ko…

Book ID: 120745464
Publisher: Springer
Year: 2013
Tongue: English
Weight: 225 KB
Volume: 54
Category: Article
ISSN: 0023-1584
DOI: 10.1134/S0023158413040022

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## Abstract The number of active centers (__C__~P~) and propagation rate constant (__k__~P~) for ethylene polymerization with homogeneous catalyst LCoCl~2~ + MAO and supported catalyst LCoCl~2~/SiO~2~ + Al(__i__‐Bu)~3~, where L is 2,6‐(2,6‐(Me)~2~C~6~H~3~N = CMe)~2~C~5~H~3~N, have been determined u