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Ferrocene-Substituted Bis(imino)pyridine Iron and Cobalt Complexes: Toward Redox-Active Catalysts for the Polymerization of Ethylene

โœ Scribed by Gibson, Vernon C.; Long, Nicholas J.; Oxford, Philip J.; White, Andrew J. P.; Williams, David J.


Book ID
120019808
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
279 KB
Volume
25
Category
Article
ISSN
0276-7333

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Iron(II) coordination compounds with ฯ‰-a
โœ Marcus Seitz; Wolfgang Milius; Helmut G. Alt ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 552 KB

Coordination compounds of iron(II)chloride with bis(imino)pyridine ligands bearing -alkenyl substituents were synthesized and characterized. They can be activated with methylalumoxane (MAO) and then be used as self-immobilizing catalysts for the polymerization of ethylene. The produced polyethylene