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Ethylene polymerization over homogeneous Bis(imino)pyridine vanadium catalysts: data on the number and reactivity of active sites

✍ Scribed by Barabanov, Artem A.; Semikolenova, Nina V.; Bukatov, Gennady D.; Matsko, Mikhail A.; Zakharov, Vladimir A.

Book ID
120617321
Publisher
Springer
Year
2012
Tongue
English
Weight
246 KB
Volume
19
Category
Article
ISSN
1022-9760

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## Abstract The number of active centers (__C__~P~) and propagation rate constant (__k__~P~) for ethylene polymerization with homogeneous catalyst LCoCl~2~ + MAO and supported catalyst LCoCl~2~/SiO~2~ + Al(__i__‐Bu)~3~, where L is 2,6‐(2,6‐(Me)~2~C~6~H~3~N = CMe)~2~C~5~H~3~N, have been determined u

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## Abstract Summary: Method of polymerization inhibition by radioactive carbon monoxide (^14^CO) has been used to determine the number of active centers (__C__~P~) and propagation rate constant (__k__~P~) for ethylene polymerization with homogeneous complex 2,6‐(2,6‐(Me)~2~C~6~H~3~Nο£ΎCMe)~2~C~5~H~3~