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Kinetic features of the cobalt dihalide/methylaluminoxane catalytic system in 1,3-butadiene polymerization

✍ Scribed by Dilip Chandra Deb Nath; Christopher M. Fellows; Takeshi Shiono

Book ID
105737110
Publisher
The Polymer Society of Korea
Year
2006
Tongue
English
Weight
147 KB
Volume
14
Category
Article
ISSN
1598-5032

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Additive Effect of Triphenylphosphine on
Additive Effect of Triphenylphosphine on the Living Polymerization of 1,3-Butadiene with a Cobalt Dichloride-Methylaluminoxane Catalytic System
✍ Dilip Chandra Deb Nath; Takeshi Shiono; Tomiki Ikeda πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 101 KB

## Abstract The additive effect of triphenylphosphine (Ph~3~P) was investigated in 1,3‐butadiene polymerization with cobalt dichloride (CoCl~2~) activated by methylaluminoxane (MAO); the catalytic system resulted in slowly‐initiated living polymerization with a high __cis__‐1,4 content (about 99%)