Polymerization kinetics of 1,3-butadiene using cobalt catalytic systems
β Scribed by S.S. Medvedev(dec.); L.A. Volkov; V.S. Byrikhin; G.V. Timofeyeva
- Book ID
- 118359680
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 726 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0032-3950
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## Abstract The additive effect of triphenylphosphine (Ph~3~P) was investigated in 1,3βbutadiene polymerization with cobalt dichloride (CoCl~2~) activated by methylaluminoxane (MAO); the catalytic system resulted in slowlyβinitiated living polymerization with a high __cis__β1,4 content (about 99%)
## Abstract The reaction mechanism and subsequent kinetics for polymerization of butadiene using cobaltβbased ZieglerβNatta catalysts have been investigated by many researchers. Kinetic models developed from these investigations can be used to predict the monomer conversion quite accurately; howeve