## Abstract The polymerization kinetics of a RAFTβmediated radical polymerization inside submicron particles (30β<β__D__~p~β<β300 nm) is considered. When the time fraction of active radical period, __Ο__~A~, is larger than ca. 1%, the polymerization rate increases with reducing particle size, as fo
Kinetic Aspects of RAFT Polymerization
β Scribed by Vana, Philipp
- Book ID
- 121881771
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 227 KB
- Volume
- 248
- Category
- Article
- ISSN
- 1022-1360
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π SIMILAR VOLUMES
The UV-initiated RAFT polymerizations of a series of poly(ethylene glycol) dimethacrylates (PEGDMA) were investigated using differential scanning photocalorimetry (DPC) at room temperature. The rate of the RAFT system was much lower than that of a conventional free radical polymerization. A mild aut
## Abstract The molecular weight distribution formed in a RAFT polymerization conducted inside submicron particles (__D__~p~β<β300 nm) is considered. For small particles, the MWD at low to middle conversion might be rather broad because of the large differences in MWDs formed in different polymer p