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Fundamentals of RAFT Miniemulsion Polymerization Kinetics

✍ Scribed by Tobita, Hidetaka


Book ID
120661586
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
437 KB
Volume
288
Category
Article
ISSN
1022-1360

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πŸ“œ SIMILAR VOLUMES


RAFT Miniemulsion Polymerization Kinetic
✍ Hidetaka Tobita πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 845 KB

## Abstract The polymerization kinetics of a RAFT‐mediated radical polymerization inside submicron particles (30 < __D__~p~ < 300 nm) is considered. When the time fraction of active radical period, __Ο•__~A~, is larger than ca. 1%, the polymerization rate increases with reducing particle size, as fo

RAFT Miniemulsion Polymerization Kinetic
✍ Hidetaka Tobita πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 483 KB

## Abstract The molecular weight distribution formed in a RAFT polymerization conducted inside submicron particles (__D__~p~ < 300 nm) is considered. For small particles, the MWD at low to middle conversion might be rather broad because of the large differences in MWDs formed in different polymer p

RAFT miniemulsion polymerization of meth
✍ Lei Yang; Yingwu Luo; Xinzhi Liu; Bogeng Li πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 English βš– 600 KB

It has been well documented that RAFT miniemulsion polymerization has broader molecular weight distribution, compared with its bulk polymerization counterpart. Interestingly, it was found that the PDI value of RAFT miniemulsion polymerization of methyl methacrylate (MMA) mediated by 2-cyranoprop-2-y

RAFT Inverse Miniemulsion Polymerization
✍ Genggeng Qi; Christopher W Jones; F. Joseph Schork πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 184 KB

## Abstract RAFT inverse miniemulsion polymerization is demonstrated for the first time as an alternate way to synthesize hydrophilic polymer latexes. The kinetic behavior of inverse RAFT miniemulsion polymerization of acrylamide is similar to that observed in aqueous RAFT solution polymerization.