## Abstract The polymerization kinetics of a RAFTβmediated radical polymerization inside submicron particles (30β<β__D__~p~β<β300 nm) is considered. When the time fraction of active radical period, __Ο__~A~, is larger than ca. 1%, the polymerization rate increases with reducing particle size, as fo
Fundamentals of RAFT Miniemulsion Polymerization Kinetics
β Scribed by Tobita, Hidetaka
- Book ID
- 120661586
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 437 KB
- Volume
- 288
- Category
- Article
- ISSN
- 1022-1360
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π SIMILAR VOLUMES
## Abstract The molecular weight distribution formed in a RAFT polymerization conducted inside submicron particles (__D__~p~β<β300 nm) is considered. For small particles, the MWD at low to middle conversion might be rather broad because of the large differences in MWDs formed in different polymer p
It has been well documented that RAFT miniemulsion polymerization has broader molecular weight distribution, compared with its bulk polymerization counterpart. Interestingly, it was found that the PDI value of RAFT miniemulsion polymerization of methyl methacrylate (MMA) mediated by 2-cyranoprop-2-y
## Abstract RAFT inverse miniemulsion polymerization is demonstrated for the first time as an alternate way to synthesize hydrophilic polymer latexes. The kinetic behavior of inverse RAFT miniemulsion polymerization of acrylamide is similar to that observed in aqueous RAFT solution polymerization.