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Kinetic and Thermodynamic Studies of the Reactivity of (Trimethylsilyl)diazomethane with HMo(CO) 3 (C 5 R 5 ) (R = H, Me). Estimation of the Mo−N 2 CH 2 SiMe 3 Bond Strength and Experimental Determination of the Enthalpy of Formation of (Trimethylsilyl)diazomethane

✍ Scribed by Fortman, George C.; Isrow, Derek; McDonough, James E.; Schleyer, Paul von Ragué; Schaefer, Henry F.; Scott, Brian; Kubas, Gregory J.; Kégl, Tamás; Ungváry, Ferenc; Hoff, Carl D.


Book ID
126092773
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
952 KB
Volume
27
Category
Article
ISSN
0276-7333

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The Influence of the Ligands Cp*(η5-C5Me
✍ Paul-Michael Pellny; Vladimir V. Burlakov; Wolfgang Baumann; Anke Spannenberg; U 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB 👁 1 views

The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,