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Alkyl Alkyne Mono((trimethylsilyl)cyclopentadienyl) Niobium Complexes. Synthesis and Chemical Behavior in Insertion Processes. X-ray Crystal Structures of [NbCp‘(CH 2 SiMe 3 ) 2 (Me 3 SiCCSiMe 3 )] and [NbCp‘(NAr){η 4 -CH(SiMe 3 )C(SiMe 3 )C(CH 2 SiMe 3 )CH(SiMe 3 )}], (Cp‘ = η 5 -C 5 H 4 SiMe 3 , Ar = 2,6-Me 2 C 6 H 3 ). DFT Studies of the Model Complexes [Nb(η 5 -C 5 H 5 )R 2 (HCCH)] (R = Cl, Me)

✍ Scribed by Galindo, Agustín; Gómez, Manuel; Gómez-Sal, Pilar; Martín, Avelino; del Río, Diego; Sánchez, Fernando


Book ID
121461784
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
184 KB
Volume
21
Category
Article
ISSN
0276-7333

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