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Kinetic and product hydrogen-deuterium isotope effects in ene reactions: a model for understanding apparently anomalous effects

โœ Scribed by Song, Zhiguo; Chrisope, Douglas R.; Beak, Peter


Book ID
126155056
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
382 KB
Volume
52
Category
Article
ISSN
0022-3263

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ฮฒ-deuterium kinetic isotope effects in t
โœ Kwang-Ting Liu; Yuh Wern Wu ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 251 KB

A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue