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Kinetic deuterium isotope effects as evidence for a common ion-pair intermediate in solvolytic elimination and substitution reactions of 1,1-diphenylethyl chloride

โœ Scribed by Thibblin, Alf; Sidhu, Harvinder


Book ID
127238882
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
678 KB
Volume
114
Category
Article
ISSN
0002-7863

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ฮฒ-deuterium kinetic isotope effects in t
โœ Kwang-Ting Liu; Yuh Wern Wu ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 251 KB

A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue