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Secondary Deuterium Kinetic Isotope Effect for Aquation, Solvolysis, and Isomerization Reactions of trans -[Co(en) 2 (OSMe 2 )N 3 ] 2+ , and the Resolution of a Mechanistic Anomaly

โœ Scribed by Jackson, W. G.


Book ID
126230982
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
146 KB
Volume
43
Category
Article
ISSN
0020-1669

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ฮฒ-deuterium kinetic isotope effects in t
โœ Kwang-Ting Liu; Yuh Wern Wu ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 251 KB

A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue