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Kinetic and mechanistic studies on the oxidation of sulfanilic acid by peroxomonophosphoric acid

✍ Scribed by Panigrahi, G. P. ;Nayak, R. N.


Book ID
112686326
Publisher
Springer
Year
1982
Tongue
English
Weight
168 KB
Volume
21
Category
Article
ISSN
0133-1736

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πŸ“œ SIMILAR VOLUMES


Kinetic and mechanistic studies on the o
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The kinetics of oxidation of nitrite to nitrate by peroxornonophosphoric acid in aqueous acid medium have been studied. The observed monotonic fall in rate with increasing pH of the medium has been rationalized on the basis of proton-dissociation equilibria of the substrate as well as the oxidant sp

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The kinetics of oxidation of sulfanilic acid (p-aminobenzenesulfonic acid) by hexacyanoferrate(III) in alkaline medium was studied spectrophotometrically. The reaction showed first order kinetics in hexacyanoferrate(III) and alkali concentrations and an order of less than unity in sulfanilic acid co

Oxidation of amino acids by peroxomonoph
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Aliphatic amino acids are smoothly oxidized by peroxomonophosphoric acid (PMPA) in the pH region 6-10. Kinetic studies reveal second order dependence in the amino acid not observed hitherto in any of the PMPA oxidations. Dependence in PMPA is unity. Rate-pH profile yields a maximum around pH 8. The

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✍ G. P. Panigrahi; Radhasyam Panda πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 391 KB πŸ‘ 1 views

The kinetics of dimethyl sulfoxide (DMSO) oxidation by peroxomonophosphoric acid (PMPA) in aqueous medium a t 308 K and I = 0.4 mol/dm3 follow the rate expressions In the pH range from 0 to 2, where k l and kz are 5.092 X 10-1 dm3/mol sec and = 0, respectively; in the pH range from 4 to 7, where k2

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✍ Puttaswamy; R. V. Jagadeesh πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 141 KB

## Abstract The kinetics of oxidation of sulfanilic acid (SAA) by chloramine‐B (CAB) and bromamine‐B (BAB) has been investigated in alkaline medium at 35 Β± 0.1Β°C. The oxidation reaction follows identical kinetics in the case of both the oxidants with first‐order dependence on each [oxidant]~o~ and