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Kinetic and mechanistic studies on the oxidation of hydroxylamine by a tri-bridged manganese(iv,iv) dimer in weakly acidic media

✍ Scribed by Banerjee, Saumen; Choudhury, Utpal Roy; Banerjee, Rupendranath; Mukhopadhyay, Subrata

Book ID
119972091
Publisher
The Royal Society of Chemistry
Year
2002
Tongue
English
Weight
139 KB
Volume
9
Category
Article
ISSN
1472-7773

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The title Mn IV complex, [Mn(LH 2 ) 3 ] 4 (LH 2 biguanide H 2 NC( NH)NHC( NH)NH 2 ), an authentic two-electron oxidant, quantitatively oxidizes hydrazine (H 2 NNH 2 ) to dinitrogen in the pH interval 2.00 Β± 3.50. The net four-electron oxidation of hydrazine is provided by two Mn IV as established by

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## Abstract The kinetics of a net two‐electron transfer between an authentic Mn^IV^ complex, [Mn(bigH)~3~]^4+^ (__Fig.β€…1__; bigH = biguanide = C~2~N~5~H~7~), and nitrite in aqueous solution in the pH interval 2.00–3.60 is described. Stoichiometric data for the reaction clearly indicates Ξ”[Mn^IV^]/Ξ”