The title Mn IV complex, [Mn(LH 2 ) 3 ] 4 (LH 2 biguanide H 2 NC( NH)NHC( NH)NH 2 ), an authentic two-electron oxidant, quantitatively oxidizes hydrazine (H 2 NNH 2 ) to dinitrogen in the pH interval 2.00 ± 3.50. The net four-electron oxidation of hydrazine is provided by two Mn IV as established by
Mechanistic Investigation of the Oxidation of Glyoxylic and Pyruvic Acids by Tris(biguanide)manganese(IV) in Weakly Acidic Aqueous Media
✍ Scribed by Basab Bijayi Dhar; Ritam Mukherjee; Subrata Mukhopadhyay; Rupendranath Banerjee
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 108 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-1948
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