𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mechanistic Studies on the Oxidation of Hydroquinone by an Oxo-bridged Diiron(III,III) Complex in Weakly Acidic Aqueous Media

✍ Scribed by Jhimli Bhattacharyya; Subrata Mukhopadhyay

Publisher
Springer
Year
2006
Tongue
English
Weight
294 KB
Volume
31
Category
Article
ISSN
0340-4285

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Mechanistic Studies on the Oxidation of
Mechanistic Studies on the Oxidation of Nitrite by a ΞΌ-Oxodiiron(III,III) Complex in Aqueous Acidic Media
✍ Jhimli Bhattacharyya; Subrata Mukhopadhyay πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 147 KB πŸ‘ 1 views

## Abstract Examined in this study is the kinetics of a net 2e^βˆ’^ transfer between [Fe~2~(__ΞΌ__‐O)(phen)~4~(H~2~O)~2~]^4+^ (1) and its hydrolytic derivatives [Fe~2~(__ΞΌ__‐O)(phen)~4~(H~2~O)(OH)]^3+^ (2) and [Fe~2~(__ΞΌ__‐O)(phen)~4~(OH)~2~]^2+^ (3) with $\rm{{{NO}}\_{{2}}^ - }$ in aqueous media and

Kinetic and Mechanistic Studies on the O
Kinetic and Mechanistic Studies on the Oxidation of Nitrogen(III) (HNO2/) by the Tris(biguanide)manganese(IV) Ion in Aqueous Acidic Media
✍ Amit Das; Subrata Mukhopadhyay πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 124 KB πŸ‘ 2 views

## Abstract The kinetics of a net two‐electron transfer between an authentic Mn^IV^ complex, [Mn(bigH)~3~]^4+^ (__Fig.β€…1__; bigH = biguanide = C~2~N~5~H~7~), and nitrite in aqueous solution in the pH interval 2.00–3.60 is described. Stoichiometric data for the reaction clearly indicates Ξ”[Mn^IV^]/Ξ”

Mechanistic Studies on the Oxidation of
Mechanistic Studies on the Oxidation of Glyoxylic and Pyruvic Acid by a [Mn4O6]4+ Core in Aqueous Media: Kinetics of Oxo-Bridge Protonation
✍ Suranjana Das; Jhimli Bhattacharyya; Subrata Mukhopadhyay πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 German βš– 108 KB πŸ‘ 1 views

In aqueous media (pH 2.5 -6.0), the Mn IV tetramer [Mn 4 (m-O) 6 A C H T U N G T R E N N U N G (bipy) 6 ] 4+ (1 4+ ; bipy = 2,2'-bipyridine) oxidizes both glyoxylic and pyruvic acid to formic and acetic acid, respectively, under formation of CO 2 . Kinetics studies suggest that the species 1 4+ , it