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Kinetic and Electron Spin Resonance Analysis of RAFT Polymerization of Styrene

✍ Scribed by Calitz, F. M.; Tonge, M. P.; Sanderson, R. D.

Book ID
119979138
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
63 KB
Volume
36
Category
Article
ISSN
0024-9297

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Kinetic study of radical polymerization
Kinetic study of radical polymerization of dialkyl fumarates using electron spin resonance spectroscopy
✍ Akikazu Matsumoto; Yoshinori Sano; Masahiro Yoshioka; Takayuki Otsu πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 628 KB

The radical polymerization of dialkyl fumarates (DRF) bearing various ester alkyl groups was kinetically studied. The propagation and termination rate constants were determined using electron spin resonance (ESR) spectroscopy. The introduction of the bulky ester alkyl groups such as a tert-butyl gro