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Kinetic and electron spin resonance studies on radical polymerization of isopropenyl acetate

โœ Scribed by Kuwae, Yoko; Kamachi, Mikiharu; Nozakura, Shunichi

Book ID
127203444
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
501 KB
Volume
19
Category
Article
ISSN
0024-9297

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Kinetic study of radical polymerization
Kinetic study of radical polymerization of dialkyl fumarates using electron spin resonance spectroscopy
โœ Akikazu Matsumoto; Yoshinori Sano; Masahiro Yoshioka; Takayuki Otsu ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 628 KB

The radical polymerization of dialkyl fumarates (DRF) bearing various ester alkyl groups was kinetically studied. The propagation and termination rate constants were determined using electron spin resonance (ESR) spectroscopy. The introduction of the bulky ester alkyl groups such as a tert-butyl gro