KEu2Cl6 and K1.6Eu1.4Cl5: Two New Mixed-Valent Europium Chlorides.
β Scribed by Claudia Wickleder
- Book ID
- 101935529
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Two novel chlorobismuthate(III) complexes [8-hydroxyquinolinium] 2) have been synthesized in solution and characterized by single-crystal X-ray diffraction. The structure of 1 contains 1-D inorganic zigzag chains formed by BiCl 6 octahedra and KCl 4 O 3 decahedra with organic 8-hydroxyquinolinium ca
## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and βtantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cpβ²)Cl~2~}~2~(ΞΌβ1,__i__βNC~6~H~4~N)] [Cpβ² = Ξ·^5^βC~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cpβ² = Ξ·^5^βC~5~H~4~SiMe~3