✦ LIBER ✦

Synthesis and optical properties of two novel chlorobismuthate(III) complexes: [8-Hydroxyquinolinium]4K2[BiCl6]2·6H2O (1) and [8-hydroxyquinolinium]6[Bi2Cl10][BiCl5(H2O)]·6H2O(2)

✍ Scribed by Yong-Jing Wang; Li Xu

Publisher: Elsevier Science
Year: 2008
Tongue: English
Weight: 453 KB
Volume: 875
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2007.06.003

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✦ Synopsis

Two novel chlorobismuthate(III) complexes [8-hydroxyquinolinium] 2) have been synthesized in solution and characterized by single-crystal X-ray diffraction. The structure of 1 contains 1-D inorganic zigzag chains formed by BiCl 6 octahedra and KCl 4 O 3 decahedra with organic 8-hydroxyquinolinium cations binding through K-O bonds or H-bonds. And compound 2 has two different anionic units of [Bi 2 Cl 10 ] 4À and [BiCl 5 (H 2 O)] 2À . IR, UV-vis DRIS, and fluorescent spectra of two compounds were studied.

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