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ChemInform Abstract: Two New Cyclic Thioanions: (PPh4)2(1,3-P2S8) and (PPh4)2(Si2S6Cl2). New Synthetic Access Routes to PPh4(PS2Cl2) and PPh4(PS2Br2).

โœ Scribed by H. GRUBER; U. MUELLER


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure