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Ketones from Acyl Chlorides and Alkyl Aluminum Chlorides: A Selective Keto-ester Synthesis

✍ Scribed by Adkins, Homer; Scanley, Clyde

Book ID
118173880
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
438 KB
Volume
73
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Synthesis of Esters
ChemInform Abstract: Synthesis of Esters from Silyl Ethers and Acyl Chlorides: Catalysis by Quaternary Ammonium Chlorides.
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Synthesis of Esters from Silyl Ethers and Acyl Chlorides: Catalysis by Quaternary Ammonium Chlorides. -Quaternary ammonium chlorides are more efficient than other ammonium halides as catalysts in the title reaction. Acetyl chloride reacts faster than benzoyl chloride and trimethylsilyl ethers react