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Synthesis of polyfluoroaromatic ketones from polyfluoroarylzinc compounds and acyl chlorides in the presence of CuCl

โœ Scribed by A. S. Vinogradov; V. I. Krasnov; V. E. Platonov

Book ID
111465292
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
220 KB
Volume
46
Category
Article
ISSN
1070-4280

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โœ Qing-Yun Chen; Jian-Guo Chen ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 674 KB

The reactions of fluorocarbanions derived from palladium(O) mediated decomposition of ally1 esters of fluoroalkylether acids, RfC02CH2CH=CH2(Rf=C3F70[CF(CF3)CF20]nCF(CF3), n=O,l), with acyl chlorides yielded en01 esters of hemifluorinated ketones, RR'C=C(Rf)OCOCHRR', n=O, 4; n=l, 5, plus a very smal