𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Joint Rotational Analysis of 16 Vibrational States of HD80Se

✍ Scribed by O.N. Ulenikov; G.A. Onopenko; V.A. Kozinskaia; E.A. Zhabina; H. Bürger; W. Jerzembeck

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
165 KB
Volume
213
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

High-resolution Fourier transform spectra of HD 80 Se in the region of the ν 1 + ν 3 , 2ν 2 + ν 3 , 2ν 1 + ν 2 , 3ν 1 , and ν 2 + 2ν 3 absorption bands, with centers located between 4000 and 5500 cm -1 , were recorded and rovibrationally analyzed. Energies of the ( 101), ( 021), ( 210), (300), and (012) states, together with those of the formerly reported ( 010), ( 100), ( 020), ( 001), ( 120), ( 110), ( 030), ( 011), ( 200), (002), and (003) states, were jointly used as input information in a "global fit" procedure. This fit provided 161 spectroscopic parameters which reproduce 3323 observed energies with accuracies close to experimental uncertainties. These parameters are compared with those predicted from H 2 Se. Moreover, experimental band centers for HSeD are compared with those calculated theoretically.

📜 SIMILAR VOLUMES

Joint Rotational Analysis of 24 Bands of
Joint Rotational Analysis of 24 Bands of the H2Se Molecule
✍ O.N. Ulenikov; G.A. Onopenko; Hai-Lin; Jin-Hui Zhang; Ze-Yi Zhou; Qing-Shi Zhu; 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 433 KB

A global fit of all currently available rotation -vibration energies has been made for 24 vibrational states of the H 80 2 Se molecule. The resulting set of 112 parameters reproduces the initial 3516 vibration -rotation energies with a mean accuracy of 10.6 1 10 03 cm 01 . Using this model as a star

High-Resolution Rotational Analysis of D
High-Resolution Rotational Analysis of Deuterated Hypochlorous Acid: Ground State, (100), and (020) Vibrational States
✍ Jing-Jing Zheng; O.N Ulenikov; E.S Bekhtereva; Yun Ding; Sheng-Gui He; Shui-Ming 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 482 KB

The high-resolution Fourier transform spectra of the DOCl molecule were recorded and analyzed in the region of the ν 1 and 2ν 2 bands. Transitions belonging to the ν 1 and 2ν 2 bands were assigned up to J max = 55 and 46, respectively. The sets of spectroscopic parameters of the ( 100) and ( 020) vi

REMPI Spectra of Cl2: Vibrational and Ro
REMPI Spectra of Cl2: Vibrational and Rotational Analysis of the 21ΠgRydberg States of35Cl2,35Cl37Cl, and37Cl2
✍ Gı́sli Hólmar Jóhannesson; Huasheng Wang; Ágúst Kvaran 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 240 KB

Rotational contours of the (2 / 1) resonance enhanced multiphoton ionization (REMPI) spectra of the vibrational bands corresponding to the 2 1 P g R X transitions in 35 Cl 2 , 35 Cl 37 Cl, and 37 Cl 2 for the natural abundance of isotopes have been recorded at room temperature. Vibrational bands con