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Joint Rotational Analysis of 24 Bands of the H2Se Molecule

✍ Scribed by O.N. Ulenikov; G.A. Onopenko; Hai-Lin; Jin-Hui Zhang; Ze-Yi Zhou; Qing-Shi Zhu; R.N. Tolchenov

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 433 KB
Volume: 189
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1997.7498

No coin nor oath required. For personal study only.

✦ Synopsis

A global fit of all currently available rotation -vibration energies has been made for 24 vibrational states of the H 80 2 Se molecule. The resulting set of 112 parameters reproduces the initial 3516 vibration -rotation energies with a mean accuracy of 10.6 1 10 03 cm 01 . Using this model as a starting point, the rotational fine structure of the extremely weak local mode bands ( 13 / ; 1 ) / ( 13 0 ; 1) and (06 / ; 0 ) /( 06 0 ; 0 ) could be analyzed; the results are discussed.

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