The high-resolution Fourier transform spectrum of the DO 35 Cl molecule was recorded and analyzed in the region of the two lowest D-O overtone bands, 2ν 1 and 3ν 1 . Because of the presence of strong resonance interactions, the influence of the (130) state on the (200) state, and also that of the (
High-Resolution Rotational Analysis of Deuterated Hypochlorous Acid: Ground State, (100), and (020) Vibrational States
✍ Scribed by Jing-Jing Zheng; O.N Ulenikov; E.S Bekhtereva; Yun Ding; Sheng-Gui He; Shui-Ming Hu; Xiang-Huai Wang; Qing-Shi Zhu
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 482 KB
- Volume
- 209
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The high-resolution Fourier transform spectra of the DOCl molecule were recorded and analyzed in the region of the ν 1 and 2ν 2 bands. Transitions belonging to the ν 1 and 2ν 2 bands were assigned up to J max = 55 and 46, respectively. The sets of spectroscopic parameters of the ( 100) and ( 020) vibrational states obtained from the fit reproduce their energies derived from the experimental data with accuracies close to experimental uncertainties.
📜 SIMILAR VOLUMES
The rotational structure in three fundamental bands nu3, nu5, and nu6 of 13CHD3 has been analyzed. As this study evidently is the first high-resolution investigation on the spectrum of this molecule, the determination of the ground state rotational constants was the necessary first step. The nu5 ban