✦ LIBER ✦

Jet spectroscopy of anthracene-alkane complexes

✍ Scribed by R.Jefferson Babbitt; Michael R. Topp

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 688 KB
Volume: 135
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)85139-4

No coin nor oath required. For personal study only.

✦ Synopsis

The fluorescence excitation spectra are reported for complexes of anthracene with n-alkanes. The spectra have only weak lowfrequency mode structure, which indicates that the complexation geometries are stable with respect to excitation of the anthracene host. At the 2: 1 complexation Ievei, the spectra indicate that the complexation geometry changes over from tram, which is favoured for short alkanes, to the cis form for alkanes longer than heptane. This behaviour is attributed to increased guest-guest interaction, which favours the formation of alkane dimers on the anthracene surface.

📜 SIMILAR VOLUMES

Dual fluorescence of the jet-cooled anth

Dual fluorescence of the jet-cooled anthracene-dialkylaniline complexes

✍ F. Piuzzi; A. Tramer 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 537 KB

Anthracene-argon complexes in a superson

Anthracene-argon complexes in a supersonic jet; spectra and lifetimes

✍ T.R. Hays; W. Henke; H.L. Selzle; E.W. Schlag 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 565 KB

Conformation dependence of electron tran

Conformation dependence of electron transfer in jet-cooled anthracene complexes with aniline derivatives

✍ F. Piuzzi; V. Brenner; P. Millié; A. Tramer 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 579 KB

Rotational spectroscopy of jet-cooled mo

Rotational spectroscopy of jet-cooled molecular ions and ion complexes

✍ Yasuhiro Ohshima; Yasuki Endo 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 433 KB

Rotational spectra of the molecular ions HOCO ÷ and HOCS ÷, and the ion complexes, D~--Ar and sym-D2H÷-Ar were observed in a supersonic-jet expansion by using a Fabry-Perot type Fourier-transform microwave spectrometer cooperated with a pulsed discharge nozzle. Ion-formation efficiency for HOCS ÷ re

Picosecond spectroscopy of charge-transf

Picosecond spectroscopy of charge-transfer processes. Photochemistry of anthracene-tetranitromethane EDA complexes

✍ J.M. Masnovi; J.C. Huffman; J.K. Kochi; E.F. Hilinski; P.M. Rentzepis 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 671 KB

The temporal sequence of events that follow 532 nm excitation of electron donor-acceptor. EDA. complexes of several substituted anthracenes with tetranitromethane is monitored by means of picosecond spectroscopy. Excitation of the charge-transfer band of these EDA complexes produces high yields of 1

Hole-burning spectra of the isomeric for

Hole-burning spectra of the isomeric forms of jet-cooled anthracene complexes with aniline derivatives

✍ F. Piuzzi 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 739 KB

Fluorescence-excitation spectra and hole-burning spectra are recorded for jet-cooled complexes of anthracene with dimethylaniline (DMA) and dimethyl-ptoluidine (DMPT). The existence of isomeric forms (two in the first and three in the latter case) is evidenced. One of these forms (E form) showing br