Isotope effects upon the kinetic of ion-molecule reactions: Kr+ + HD

✍ Scribed by S. Chivalak; P.M. Hierl

• Book ID: 103016263
• Publisher: Elsevier Science
• Year: 1977
• Tongue: English
• Weight: 370 KB
• Volume: 45
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(77)85219-6

✦ Synopsis

The reaction of Kr* with HD exhibits a very unusual kinetic isotope effect. The ratio KrH+/KrD'begins near unity zt the lowest collision energy, passes through a maximum of nearly 2.5 at 0.7 eV (c.m.1, and then decreases to about 0.25 at 3 eV (c.m.).