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Kinetics of ion-molecule reactions – The early years

✍ Scribed by Harrison, Alex G.


Book ID
122189863
Publisher
Elsevier Science
Year
2015
Tongue
English
Weight
1022 KB
Volume
377
Category
Article
ISSN
1387-3806

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Isotope effects upon the kinetic of ion-
✍ S. Chivalak; P.M. Hierl 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 370 KB

The reaction of Kr\* with HD exhibits a very unusual kinetic isotope effect. The ratio KrH+/KrD'begins near unity zt the lowest collision energy, passes through a maximum of nearly 2.5 at 0.7 eV (c.m.1, and then decreases to about 0.25 at 3 eV (c.m.).