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Formal kinetics of some competing bimolecular reactions, and how the kinetic isotope effect influences the distribution of isotopic molecules

✍ Scribed by G. A. Skrobogatov

Book ID
112437208
Publisher
Springer
Year
1962
Tongue
English
Weight
727 KB
Volume
11
Category
Article
ISSN
1573-9171

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πŸ“œ SIMILAR VOLUMES

Isotope effects upon the kinetic of ion-
Isotope effects upon the kinetic of ion-molecule reactions: Kr+ + HD
✍ S. Chivalak; P.M. Hierl πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 370 KB

The reaction of Kr\* with HD exhibits a very unusual kinetic isotope effect. The ratio KrH+/KrD'begins near unity zt the lowest collision energy, passes through a maximum of nearly 2.5 at 0.7 eV (c.m.1, and then decreases to about 0.25 at 3 eV (c.m.).