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Isotope Effects in Recoil Tritium Reactions with Methyl Fluoride

โœ Scribed by Lee, Edward K. C.; Rowland, F. S.


Book ID
126136763
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
836 KB
Volume
85
Category
Article
ISSN
0002-7863

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Mechanistic implications from the substi
โœ C.C. Chou; D.D. Wilkey; F.S. Rowland ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 194 KB

The reactions with CHjF of photochemically produced tritium atoms from TBr have been studied at various v+xvelengths. The energy threshold is lower and the relative yield higher for F replacement than for H repkement in CHaF. These near-threshold substitution reactions are consistent with an inversi