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Isotope effects and H/D scrambling in the fragmentation of labelled propenes

✍ Scribed by A. Y.-K. Lau; B. H. Solka; A. G. Harrison

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
214 KB
Volume
9
Category
Article
ISSN
1076-5174

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✦ Synopsis

The fragmentation reaction [C,(H, D)J+. + [C,(H, D)J+ + (H, D) has been examined in the metastable decomposition region for two pairs of labelled propenes: CH,CD=CH,, CD,CH==CD, and CD,CH=CH,, CH,CD=CD,. The results indicate that complete hydrogen scrambling occurs in the propene molecular ion prior to fragmentation. The isotope effect k,/k, is in the range 2.1 to 3.3.

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