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Isomerization of (Z)-alkenylsilanes to (E)-isomers with hydrosilane and RhI(PPh3)3

✍ Scribed by Mori, Atsunori; Takahisa, Eisuke; Nishihara, Yasushi; Hiyama, Tamejiro

Book ID
115523667
Publisher
NRC Research Press
Year
2001
Tongue
French
Weight
150 KB
Volume
79
Category
Article
ISSN
0008-4042

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πŸ“œ SIMILAR VOLUMES

Stereodivergent hydrosilylation of 1-alk
Stereodivergent hydrosilylation of 1-alkynes catalyzed by RhI(PPh3)3 leading to (E)- and (Z)-alkenylsilanes and the application to polymer synthesis
✍ Atsunori Mori; Eisuke Takahisa; Hiroshi Kajiro; Yasushi Nishihara; Tamejiro Hiya πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 50 KB

Hydrosilylation of 1-alkynes catalyzed by RhI(PPh 3 ) 3 gives (E)-and (Z)-alkenylsilanes in a stereodivergent manner by switching the reaction conditions and the order of the addition of the reagents. The reaction is also applied to the synthesis of silicon-containing polymers with (E) and (Z) main-

ChemInform Abstract: RhCl(PPh3)3/NaI Cat
ChemInform Abstract: RhCl(PPh3)3/NaI Catalyst System for Hydrosilylation of 1-Alkynes: Stereodivergent Syntheses of E- and Z-Alkenylsilanes with Heteroatom Substituents on Silicon.
✍ A. MORI; E. TAKAHISA; H. KAJIRO; K. HIRABAYASHI; Y. NISHIHARA; T. HIYAMA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 1 views

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