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Chemoselective Reactions of ( E )-1,3-Dienes: Cobalt-Mediated Isomerization to ( Z )-1,3-Dienes and Reactions with Ethylene

✍ Scribed by Timsina, Yam N.; Biswas, Souvagya; RajanBabu, T. V.


Book ID
124086877
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
664 KB
Volume
136
Category
Article
ISSN
0002-7863

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Stereospecific synthesis of (1E,3Z)- and
✍ V. Fiandanese; G. Marchese; G. Mascolo; F. Naso; L. Ronzini πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 264 KB

A new synthesis of stereodefined 1-trimeUlylsllyl-1,3-dlenes is described. The method is based on two sequential coupling reactions between Grlgnard reagents and the readily available (Z)-or (15)-l -bromo-2-phenylthloethene, In the presence of transition metal catalysts.