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Reactions of Alkynyldihaloboranes with 1,3-Dienes. 1,4-Alkynylborations and Stepwise Diels−Alder Reactions

✍ Scribed by Leung, Shun-Wang; Singleton, Daniel A.

Book ID
126834913
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
313 KB
Volume
62
Category
Article
ISSN
0022-3263

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## Abstract The Diels–Alder reaction of 4‐nitrobenzodifuroxan (NBDF) with 1‐methoxy‐3‐trimethylsilyloxy‐1,3‐butadiene has been investigated experimentally and theoretically. Treatment of NBDF with excess diene in chloroform at room temperature was found to afford a single product that contained a c