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Cobalt-Catalyzed Isomerization of 1-Alkenes to (E)-2-Alkenes with Dimethylphenylsilylmethylmagnesium Chloride and Its Application to the Stereoselective Synthesis of (E)-Alkenylsilanes

✍ Scribed by Tsuneyuki Kobayashi; Hideki Yorimitsu; Koichiro Oshima

Book ID: 112005741
Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 276 KB
Volume: 4
Category: Article
ISSN: 1861-4728
DOI: 10.1002/asia.200900111

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Hydrosilylation of 1-alkynes catalyzed by RhI(PPh 3 ) 3 gives (E)-and (Z)-alkenylsilanes in a stereodivergent manner by switching the reaction conditions and the order of the addition of the reagents. The reaction is also applied to the synthesis of silicon-containing polymers with (E) and (Z) main-