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Isomeric trans,trans-bicyclo[6.1.0]non-4-enes

✍ Scribed by Deyrup, J. A.; Betkouski, M. F.


Book ID
127357838
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
854 KB
Volume
40
Category
Article
ISSN
0022-3263

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Derivatives of trans-bicyclo[4.1.0]hept-3-ene with chlorine and bromine substituents the 7 position were synthesized and their thermal rearrangements were examined. Thermolysis of the dichloride leads to the formation of the cis-fused isomer, while heating the dibromide results in ring-expanded prod