Butenollde anlons do not react with orthoesters and butenolldes do not react with carbocatlons derived from acetals and orthoesters However double activation of the butenollde (as the carbanlon) and the alkoxyalkanes (as the stablllsed carbocatlons) leads to high yield carbon-carbon bond formation o
Ironcarbon bond formation during substrate activation by hemoproteins
✍ Scribed by D. Mansuy
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 229 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0020-1693
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✦ Synopsis
The results reflect the complexity of each system, the simultaneous presence of several species in them, the sensitivity of the complex formation equilibria on internal (structure of ligand) and external (matrix) factors. The equilibrium constants have been used for the calculation of the concentration distribution of species of different compositions.
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